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• W1990576086 startingPage "1203" @default.
• W1990576086 abstract "The synthesis of regioregular head-to-tail poly(3-hexylthiophene)s capped with aryl groups (Ar-HT-P3HTs) has been accomplished by palladium-catalyzed polycondensation of 2-bromo-3-hexylthiophene (1) via direct arylation. A variety of aryl groups are installed at the initiated end in 86%-98% selectivity using aryl bromides and iodides as capping agents. The polymerization proceeds via a two-stage process. Before monomer 1 is consumed, the competitive formation of end-capped and non-capped HT-P3HTs is operative, where the molecular weight increases linearly with monomer conversion. After 1 is consumed, the resulting polymers are coupled with each other to afford highly end-capped HT-P3HTs." @default.
• W1990576086 created "2016-06-24" @default.
• W1990576086 creator A5000779954 @default.
• W1990576086 creator A5016834374 @default.
• W1990576086 creator A5090399176 @default.
• W1990576086 date "2012-04-27" @default.
• W1990576086 modified "2023-10-10" @default.
• W1990576086 title "Synthesis of End-capped Regioregular Poly(3-hexylthiophene)s via Direct Arylation" @default.
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• W1990576086 doi "https://doi.org/10.1002/marc.201200076" @default.
• W1990576086 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22539499" @default.
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