Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990600918> ?p ?o ?g. }
- W1990600918 endingPage "12253" @default.
- W1990600918 startingPage "12246" @default.
- W1990600918 abstract "An efficient strategy for synthesis of a wide range of homo- and heterometallic polynuclear complexes is proposed. The synthesis protocol consists of a two-step one-pot reaction. The first step is the in situ generation of carboxylate anions via oxidation of aromatic aldehydes by metal nitrates in air. The aldehydes act as solvents and are also involved in redox processes. Solutions containing solely transition metal cations and aromatic carboxylates are obtained following this procedure. The second step is a tunable à la carte formation of a series of various polynuclear carboxylato complexes from solutions obtained at the former stage upon addition of different solvents. The polarity and donor properties of the solvents play a key role in determination of the nuclearities of the complexes. Hydrolytic processes can induce the formation of oxo- or hydroxo-bridges inside the polynuclear core as well. Complexes of various nuclearities are obtained: from discrete tri-, hexa-, or octanuclear units to 1D polymers. This protocol can be adapted with disconcerting simplicity to the synthesis of heterometallic species with similar molecular structures to their homometallic analogues starting from stoichiometric mixture of metal nitrates under the same reaction conditions. Detailed description of synthesis and the molecular structure of one representative complex for each series are presented in this paper. The temperature dependence of magnetic susceptibility of the heterometallic 1-D MnCo chain reveals typical behavior of a ferrimagnetic chain. The low-temperature investigations on single crystals show significant Ising type magnetic anisotropy." @default.
- W1990600918 created "2016-06-24" @default.
- W1990600918 creator A5023461212 @default.
- W1990600918 creator A5038928551 @default.
- W1990600918 creator A5039516823 @default.
- W1990600918 creator A5041185065 @default.
- W1990600918 creator A5050547836 @default.
- W1990600918 creator A5078132392 @default.
- W1990600918 date "2005-08-13" @default.
- W1990600918 modified "2023-10-18" @default.
- W1990600918 title "In Situ Generation of Carboxylate: An Efficient Strategy for a One-Pot Synthesis of Homo- and Heterometallic Polynuclear Complexes" @default.
- W1990600918 cites W1967298480 @default.
- W1990600918 cites W1967547035 @default.
- W1990600918 cites W1968468959 @default.
- W1990600918 cites W1968751790 @default.
- W1990600918 cites W1973934105 @default.
- W1990600918 cites W1974545223 @default.
- W1990600918 cites W1975810601 @default.
- W1990600918 cites W1980338866 @default.
- W1990600918 cites W1981600196 @default.
- W1990600918 cites W1988433378 @default.
- W1990600918 cites W1997258277 @default.
- W1990600918 cites W2005692171 @default.
- W1990600918 cites W2006038032 @default.
- W1990600918 cites W2015893297 @default.
- W1990600918 cites W2019657206 @default.
- W1990600918 cites W2030592304 @default.
- W1990600918 cites W2031541386 @default.
- W1990600918 cites W2032663734 @default.
- W1990600918 cites W2034451182 @default.
- W1990600918 cites W2044952194 @default.
- W1990600918 cites W2047437667 @default.
- W1990600918 cites W2049029500 @default.
- W1990600918 cites W2057874777 @default.
- W1990600918 cites W2061832845 @default.
- W1990600918 cites W2061869556 @default.
- W1990600918 cites W2062485571 @default.
- W1990600918 cites W2062903599 @default.
- W1990600918 cites W2065850201 @default.
- W1990600918 cites W2069856937 @default.
- W1990600918 cites W2072908546 @default.
- W1990600918 cites W2073947588 @default.
- W1990600918 cites W2081390849 @default.
- W1990600918 cites W2082379470 @default.
- W1990600918 cites W2089796724 @default.
- W1990600918 cites W2091599683 @default.
- W1990600918 cites W2092599714 @default.
- W1990600918 cites W2128061562 @default.
- W1990600918 cites W2135374860 @default.
- W1990600918 cites W2138931194 @default.
- W1990600918 cites W2149997038 @default.
- W1990600918 cites W2610617331 @default.
- W1990600918 doi "https://doi.org/10.1021/ja050451p" @default.
- W1990600918 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16131202" @default.
- W1990600918 hasPublicationYear "2005" @default.
- W1990600918 type Work @default.
- W1990600918 sameAs 1990600918 @default.
- W1990600918 citedByCount "110" @default.
- W1990600918 countsByYear W19906009182012 @default.
- W1990600918 countsByYear W19906009182013 @default.
- W1990600918 countsByYear W19906009182014 @default.
- W1990600918 countsByYear W19906009182015 @default.
- W1990600918 countsByYear W19906009182016 @default.
- W1990600918 countsByYear W19906009182017 @default.
- W1990600918 countsByYear W19906009182018 @default.
- W1990600918 countsByYear W19906009182019 @default.
- W1990600918 countsByYear W19906009182021 @default.
- W1990600918 countsByYear W19906009182022 @default.
- W1990600918 crossrefType "journal-article" @default.
- W1990600918 hasAuthorship W1990600918A5023461212 @default.
- W1990600918 hasAuthorship W1990600918A5038928551 @default.
- W1990600918 hasAuthorship W1990600918A5039516823 @default.
- W1990600918 hasAuthorship W1990600918A5041185065 @default.
- W1990600918 hasAuthorship W1990600918A5050547836 @default.
- W1990600918 hasAuthorship W1990600918A5078132392 @default.
- W1990600918 hasConcept C115260700 @default.
- W1990600918 hasConcept C121332964 @default.
- W1990600918 hasConcept C144082473 @default.
- W1990600918 hasConcept C178790620 @default.
- W1990600918 hasConcept C179104552 @default.
- W1990600918 hasConcept C185592680 @default.
- W1990600918 hasConcept C21951064 @default.
- W1990600918 hasConcept C2778074193 @default.
- W1990600918 hasConcept C32546565 @default.
- W1990600918 hasConcept C544153396 @default.
- W1990600918 hasConcept C55904794 @default.
- W1990600918 hasConcept C62520636 @default.
- W1990600918 hasConcept C779372 @default.
- W1990600918 hasConceptScore W1990600918C115260700 @default.
- W1990600918 hasConceptScore W1990600918C121332964 @default.
- W1990600918 hasConceptScore W1990600918C144082473 @default.
- W1990600918 hasConceptScore W1990600918C178790620 @default.
- W1990600918 hasConceptScore W1990600918C179104552 @default.
- W1990600918 hasConceptScore W1990600918C185592680 @default.
- W1990600918 hasConceptScore W1990600918C21951064 @default.
- W1990600918 hasConceptScore W1990600918C2778074193 @default.
- W1990600918 hasConceptScore W1990600918C32546565 @default.
- W1990600918 hasConceptScore W1990600918C544153396 @default.