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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990604699> ?p ?o ?g. }

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• W1990604699 startingPage "1383" @default.
• W1990604699 abstract "Abstract magnified image The dynamic complex cis ‐ P,P ′‐(η 5 ‐cyclopentadienyl)‐{5,17‐bis(diphenylphosphino)‐25,26,27, 28‐tetrabenzyloxycalix[4]arene}nickel(II) tetrafluoroborate ( 2 ) in which the PNiP plane undergoes a rapid fanning motion was assessed in the cross‐coupling reacting between phenylmagnesium bromide (PhMgBr) and aryl halides (ArX). TOFs, of up to 21250 mol(converted ArBr)⋅mol( 2 ) −1 ⋅h −1 , were obtained with electron‐rich as well as congested bromoarenes using catalyst loadings as low as 1×10 −3 mol%, provided that the reactions were carried out at 100 °C in dioxane with a PhMgBr/ArX ratio of 2:1. The high activities observed contrast with those observed for triphenylphosphine‐based catalysts and furthermore, outperforms the fastest diphosphine‐based catalysts reported, a behaviour which is likely to rely on a bite angle effect." @default.
• W1990604699 created "2016-06-24" @default.
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• W1990604699 date "2009-06-01" @default.
• W1990604699 modified "2023-10-08" @default.
• W1990604699 title "Efficient, Nickel‐Catalysed Kumada–Tamao–Corriu Cross‐ Coupling with a Calix[4]arene‐Diphosphine Ligand" @default.
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• W1990604699 doi "https://doi.org/10.1002/adsc.200800759" @default.
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