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• W1990611361 abstract "We have used dissipative particle dynamics (DPD) to simulate the system of cetyltrimethylammonium bromide (CTAB) monolayer at the oil/water interface. The interfacial properties (interfacial density, interfacial thickness, and interfacial tension), structural properties (area compressibility modulus, end to end distance, and order parameter), and their dependence on the oil/water ratio and the surfactant concentration were investigated. Three different microstructures, spherical oil in water (o/w), interfacial phase, and water in oil (w/o), can be clearly observed with the oil/water ratio increasing. Both the snapshots and the density profiles of the simulation show that a well defined interface exists between the oil and water phases. The interface thickens with CTAB concentration and oil/water ratio. The area compressibility modulus decreases with an increase in the oil/water ratio. The CTAB molecules are more highly packed at the interface and more upright with both concentration and oil/water ratio. The root mean square end-to-end distance and order parameter have a very weak dependence on the oil/water ratio. But both of them show an increase with CTAB concentration, indicating that the surfactant molecules at the interface become more stretched and more ordered at high concentration. As CTAB concentration increases further, the order parameter decreases instead because the bending of the interface. At the same time, it is shown that CTAB has a high interfacial efficiency at the oil/water interface." @default.
• W1990611361 created "2016-06-24" @default.
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• W1990611361 date "2011-09-01" @default.
• W1990611361 modified "2023-10-01" @default.
• W1990611361 title "Investigation of interfacial and structural properties of CTAB at the oil/water interface using dissipative particle dynamics simulations" @default.
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• W1990611361 doi "https://doi.org/10.1016/j.jcis.2011.05.078" @default.
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