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- W1990626441 abstract "The anion radical of V2(CO)8(μ-PPh2)2 and the cation radical of Mn2(CO)8(μ-AsPh2)2 are generated by chemical reduction of the vanadium complex with LiBHEt3 or potassium naphthalenide and by radiochemical oxidation of the manganese complex in frozen Freon mixture, respectively. Their anisotropic ESR spectra show that the V2P2 and the Mn2As2 rhomboids are planar. Their g and hyperfine splitting tensors are analyzed on the basis of a qualitative molecular orbital scheme for metal-metal bonds developed from a hypothesis that metal-ligand interactions are larger than metal-metal interactions. The odd electron orbital of V2(CO)8(μ-PPh2)2−· is assigned to the metal-metal π* MO and the odd electron density on the vanadium d AO is estimated as 0.21. The odd electron of Mn2(CO)8(μ-AsPh2)2+· is concluded to be accomodated in the metal-metal σ* MO and odd electron densities on manganese and arsenic atoms are evaluated as ρ(Mn d)=0.25 and ρ(As p)=0.08 or 0.16, respectively. Order of magnitude estimates of orbital ener..." @default.
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- W1990626441 date "1982-11-01" @default.
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- W1990626441 title "Electronic Structure of V2(CO)8(μ-PPh2)2and Mn2(CO)8(μ-AsPh2)2by Electron Spin Resonance Study of Their Ion Radicals" @default.
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- W1990626441 doi "https://doi.org/10.1246/bcsj.55.3417" @default.
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