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- W1990634458 abstract "Fe(CN)5ampy3− (ampy = 4-aminopyridine) complex was unstable at pH ≤ 4 with respect to the dissociation due to the protonations of the complex. The first protonation on the 4-aminopyridine ligand at pKa = 3.2 resulted in a ≅ 150-fold in crease in rate of dissociation as compared to that of the complex in the neutral solution. However, further protonation of the complex on the cyanide ligand at pKa = 1.5 in creased the rate only slightly. The large in crease in the rate constant of dissociation for Fe(CN)5ampyH2− complex suggests that in the transition state the proton is likely shifted from the amino group and becomes coordinated to a pair of dπ electrons directed at the face of the coordinated octahedron." @default.
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- W1990634458 date "2001-10-01" @default.
- W1990634458 modified "2023-09-24" @default.
- W1990634458 title "Acid Catalyzed Dissociation of 4-Aminopyridine Complex of Pentacyanoferrate (II)" @default.
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- W1990634458 doi "https://doi.org/10.1002/jccs.200100122" @default.
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