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• W1990647518 abstract "The adsorption of dodecanethiol [CH3(CH2)11SH] films on Cu(110) by vapor deposition under ultrahigh vacuum conditions has been studied by means of thermal desorption spectroscopy, scanning tunneling microscopy, X-ray photoelectron spectroscopy (XPS), and low-energy electron diffraction with a special emphasis on the structural changes accompanying the transition from a physisorbed monolayer to a chemisorbed saturation structure. Adsorption at 110 K leads to the formation of an ordered physisorbed layer with flat-lying thiol molecules. Upon room-temperature deposition, initially an ordered pinstripe phase is formed which may be a molecular double layer. This layer transforms with time into a stable saturation structure of upright-tilted thiolates in a local c(2 × 2) arrangement that exhibits a long-range c(12 × 16) modulation, attributed to a Moire pattern. The XPS measurements show that the room-temperature saturation structure contains a fraction of sulfide species formed by partial decomposition and des..." @default.
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• W1990647518 date "2002-06-07" @default.
• W1990647518 modified "2023-09-23" @default.
• W1990647518 title "Adsorption of Dodecanethiol on Cu(110): Structural Ordering upon Thiolate Formation" @default.
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• W1990647518 doi "https://doi.org/10.1021/la025661j" @default.
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