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• W1990651921 abstract "The formation of tar during biomass gasification limits the use of the product gas in small scale CHP units like gas engines. Catalytic partial oxidation can be applied to remove tar and convert it into fuel gas by using a catalyst under sub-stoichiometric addition of oxygen. In the present study, different catalyst materials, i.e. several perovskite-type materials and one Ni-based catalyst, which shall be used in combination with an oxygen carrier material, were investigated in lab-scale experiments regarding their catalytic activity in partial oxidation of naphthalene as model tar compound. Furthermore, the influence of the trace substances HCl, KCl, and H2S on the performance of the Ni-based catalyst being the best performing catalyst was tested. Since the Ni-based catalyst is significantly poisoned by H2S, it was also tested in combination with a CuO-based sorbent. In addition to H2S reduction, the sorbent increased the catalytic activity of the entire system significantly, so that naphthalene was almost completely converted at temperatures above 450 °C despite the presence of 140 ppm H2S." @default.
• W1990651921 created "2016-06-24" @default.
• W1990651921 creator A5017306399 @default.
• W1990651921 creator A5025676730 @default.
• W1990651921 date "2015-03-01" @default.
• W1990651921 modified "2023-10-16" @default.
• W1990651921 title "Investigation of various catalysts for partial oxidation of tar from biomass gasification" @default.
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• W1990651921 doi "https://doi.org/10.1016/j.apcata.2015.01.012" @default.
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