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• W1990653537 abstract "New 1,2-disubstituted ferrocenyl stibines viz. containing -CH2NR or -CH2NHR pendant arm at the ortho-position have been synthesized and characterized by various physicochemical methods. These new ferrocenylstibines were prepared by the nucleophilic substitution reaction of diphenyl[(N,N,N-trimethylaminomethylferrocenyl)iodide]stibine by different primary amines and secondary heterocyclic amines viz. furan-2-ylmethylamine, p-aminoacetophenone, 3-(1-hydroxyethyl)-aniline, 4-hydroxypiperidine, 1-ethylpiperazine and 4-(4-bromophenyl)-4-hydroxypiperidine. Molecular structure of stibine (2), (3), (5) and (7) have been determined by X-ray crystallography. Stibine (2), (5) and (7) show a weak hypervalent Sb–N interaction while stibine (3) does not show this interaction in solid state." @default.
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• W1990653537 date "2009-06-01" @default.
• W1990653537 modified "2023-10-01" @default.
• W1990653537 title "New 1,2-disubstituted ferrocenyl stibines containing N-heterocyclic pendant arm: Sb–N hypervalent compounds" @default.
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• W1990653537 doi "https://doi.org/10.1016/j.jorganchem.2009.01.051" @default.
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