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- W1990663009 abstract "The high-resolution gas-phase Fourier transform infrared spectrum of the doubly 15N-substituted isocyanogen, C15NC15N, has been measured in the spectral regions 160–240 cm−1 and 390–1110 cm−1 with unapodized resolutions of 0.0017 and 0.0021 cm−1 respectively. In these experiments we were able to measure the band systems due to the excitation of the bending modes ν5 and ν4 at 190.9 cm−1 and 458.1 cm−1, a combination band system of the two bending modes ν4 + ν5 at 649.7 cm−1, as well as two band systems arising from a Fermi interaction between the twofold excited bending mode 2ν4 and the stretching mode ν3 at 869.9 cm−1 and 960.2 cm−1 respectively. Furthermore, we have measured and assigned pure rotational transitions of C15NC15N in the vibrational ground state and in excited vibrational bending states lying in the microwave and the millimeter wave region between 19.9 and 20.2 GHz, 29.9 and 30.4 GHz and 120 and 440 GHz. Constants of a power series in J(J + 1) for numerous rovibrational subbands, as well as accurate molecular constants using the effective hamiltonian for linear polyatomic molecules, defined by Yamada et al. [J. Mol. Spectrosc., 112 (1985) 347], were determined." @default.
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- W1990663009 date "1996-02-01" @default.
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- W1990663009 title "Rotational and rovibrational spectrum of C15NC15N in the region of the bending modes ν4, ν5, the combination band ν4 + ν5 and the Fermi interacting modes ν3, 2ν4" @default.
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- W1990663009 doi "https://doi.org/10.1016/0022-2860(95)09107-6" @default.
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