Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990673463> ?p ?o ?g. }
- W1990673463 endingPage "4642" @default.
- W1990673463 startingPage "4633" @default.
- W1990673463 abstract "A monocationic plug−socket connector that is composed, at the molecular level, of three components, (1) a secondary dialkylammonium center (CH2NH2+CH2), which can play the role of a plug toward dibenzo[24]crown-8 (DB24C8), (2) a rigid and conducting biphenyl spacer, and (3) 1,4-benzo-1,5-naphtho[36]crown-10 (BN36C10), capable of playing the role of a socket toward a 4,4‘-bipyridinium dicationic plug, was synthesized and displays the ability to act as a plug−socket connector. The fluorescent signal changes associated with the 1,5-dioxynaphthalene unit of its BN36C10 portion were monitored to investigate the association of this plug−socket connector with the complementary socket and plug compounds. The results indicate that (1) the CH2NH2+CH2 part of the molecular connector can thread DB24C8 in a trivial manner and (2) the BN36C10 ring of the connector can be threaded by a 1,1‘-dioctyl-4,4‘-bipyridinium ion only after the CH2NH2+CH2 site is occupied by a DB24C8 ring. The two connections of the three-component assembly are shown to be controlled reversibly by acid/base and red/ox external inputs, respectively. The results obtained represent a key step for the design and construction of a self-assembling supramolecular system in which the molecular electron source can be connected to the molecular electron drain by a molecular elongation cable." @default.
- W1990673463 created "2016-06-24" @default.
- W1990673463 creator A5003915113 @default.
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- W1990673463 creator A5089719740 @default.
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- W1990673463 date "2007-03-28" @default.
- W1990673463 modified "2023-10-18" @default.
- W1990673463 title "A Molecular Plug−Socket Connector" @default.
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