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- W1990678596 abstract "The structure of a new gibberellin, GA99, isolated from Spinach plants has been determined to be 2β-hydroxy-GA19 (6) by synthesis from gibberellic acid. The key steps in the preparation involved the reduction under Luche conditions of a δ1(10)-2-one derivative to furnish the critical 2β-stereochemistry, intramolecular cyclopropanation of the δ1(10) bond by a 4α-diazoacetyl group followed by LiNH3 reduction, and then oxidative cleavage of the resulting cyclopentanone by oxygenation of the derived potassium enolate." @default.
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- W1990678596 date "1996-01-01" @default.
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- W1990678596 title "Structure determination and synthesis of a new gibberellin, GA99, from spinach plants: 2β-hydroxy-GA19" @default.
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- W1990678596 doi "https://doi.org/10.1016/0040-4039(95)02252-x" @default.
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