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• W1990681970 abstract "Near a surface an atom acquires a permanent electric dipole. When we take into account the presence of neighbors, three processes simultaneously contribute to the reduction of its dipole: a dipolar, a quadrupolar, and a quantum one. These depolarization processes of an adatom by its neighbors are particularly important for large coverage of the surface. We discuss them and give the expression for the dipole moment induced by such effects on an adatom. We then express the formulas with respect to the dipolar and quadrupolar polarizability and a nonlinear coefficient ensuremath{eta}, which leads us to propose numerical estimates of these effects for hydrogen and inert gases. For realistic distances of the adatom from the surface and from its neighbor, we show that the dipolar term has the greatest influence and that the quadrupolar-induced term always has a negligible influence on the neighboring adatom." @default.
• W1990681970 created "2016-06-24" @default.
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• W1990681970 date "1986-11-01" @default.
• W1990681970 modified "2023-10-17" @default.
• W1990681970 title "Magnitude of van der Waals<i>–</i>induced dipole moments in physisorption" @default.
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• W1990681970 doi "https://doi.org/10.1103/physreva.34.3587" @default.
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