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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990682013> ?p ?o ?g. }

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• W1990682013 abstract "A Fourier Transform infrared spectrometer has been attached to an ultrahigh vacuum (UHV) apparatus in order to perform reflection-absorption infrared Spectroscopy (RAIRS) of adsorbed species on well-defined surfaces. An infrared spectrum of carbon monoxide (CO) adsorbed at 90 K on Cu(111) has been measured using a resolution of 2 cm−1 and a measuring time of 60 s. Coverages below 1 % of a monolayer are easily detectable. Tetracyanoethylene (TCNE) has been adsorbed at various coverages at 100 K on Cu(111). Strongly red-shifted CN stretchings modes due to charged TCNE adspecies are observed at low coverage. The RAIRS spectrum of the condensed phase is characteristic of crystalline TCNE. Finally, isotopically labeled 12C and 13C acetonitrile (CH3CN) has been adsorbed on Cu(111) as multilayers. Shifts caused by isotopic labeling as small as 3 cm−1 are easily detected." @default.
• W1990682013 created "2016-06-24" @default.
• W1990682013 creator A5034477420 @default.
• W1990682013 date "1987-01-01" @default.
• W1990682013 modified "2023-09-23" @default.
• W1990682013 title "Reflection-absorption infrared spectroscopy of adsorbates on a Cu(111) single crystal surface" @default.
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• W1990682013 doi "https://doi.org/10.1016/0368-2048(87)87008-1" @default.
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