Matches in SemOpenAlex for { <https://semopenalex.org/work/W1990684267> ?p ?o ?g. }
- W1990684267 endingPage "3286" @default.
- W1990684267 startingPage "3280" @default.
- W1990684267 abstract "A series of sodium, potassium, rubidium, and cesium complexes of methyl tetrazolate was prepared and structurally characterized. Treatment of methyl tetrazole (MetetzH) with the group 1 hydroxides in water at ambient temperature afforded Na(Metetz)(H2O)2 (92%), K(Metetz) (92%), Rb(Metetz) (97%), and Cs(Metetz) (97%) as colorless solids after workup. These complexes were characterized by spectral and analytical methods, thermogravimetric analysis, and by X-ray crystallography. Na(Metetz)(H2O)2 adopts a structure that consists of approximately octahedrally coordinated sodium ions that form infinite chains built up by two μ2-aqua ligands and two μ2-N1,N2-tetrazolate ligands between each sodium atom. The aqua ligand hydrogen atoms engage in hydrogen bonding with uncoordinated nitrogen atoms to hold the chains together. K(Metetz) and Rb(Metetz) are isostructural, with eight-coordinate metal ions and two metal–nitrogen bonds per nitrogen atom in each Metetz ligand. Cs(Metetz) has 10-coordinate cesium ions with two cesium–nitrogen bonds to two of the Metetz ligand nitrogen atoms and three cesium–nitrogen bonds to the other two nitrogen atoms. K(Metetz), Rb(Metetz), and Cs(Metetz) exhibit new coordination modes for the tetrazolate ligand." @default.
- W1990684267 created "2016-06-24" @default.
- W1990684267 creator A5013652065 @default.
- W1990684267 creator A5029233522 @default.
- W1990684267 creator A5058898558 @default.
- W1990684267 creator A5071729996 @default.
- W1990684267 date "2008-10-01" @default.
- W1990684267 modified "2023-10-17" @default.
- W1990684267 title "Synthesis and structural characterization of heavier group 1 methyl tetrazolate complexes: New bridging coordination modes of the tetrazolate ligand" @default.
- W1990684267 cites W1966535319 @default.
- W1990684267 cites W1967929000 @default.
- W1990684267 cites W1968944406 @default.
- W1990684267 cites W1976221647 @default.
- W1990684267 cites W1976818535 @default.
- W1990684267 cites W1977100404 @default.
- W1990684267 cites W1984382545 @default.
- W1990684267 cites W1985070241 @default.
- W1990684267 cites W1988796761 @default.
- W1990684267 cites W1999612325 @default.
- W1990684267 cites W2002728263 @default.
- W1990684267 cites W2003097329 @default.
- W1990684267 cites W2007775016 @default.
- W1990684267 cites W2009941018 @default.
- W1990684267 cites W2013548901 @default.
- W1990684267 cites W2013652476 @default.
- W1990684267 cites W2014878864 @default.
- W1990684267 cites W2017533563 @default.
- W1990684267 cites W2018580343 @default.
- W1990684267 cites W2018599637 @default.
- W1990684267 cites W2018607138 @default.
- W1990684267 cites W2025511520 @default.
- W1990684267 cites W2030141832 @default.
- W1990684267 cites W2030841140 @default.
- W1990684267 cites W2032638810 @default.
- W1990684267 cites W2035150499 @default.
- W1990684267 cites W2038232512 @default.
- W1990684267 cites W2039102036 @default.
- W1990684267 cites W2042465985 @default.
- W1990684267 cites W2042604459 @default.
- W1990684267 cites W2048801245 @default.
- W1990684267 cites W2049582417 @default.
- W1990684267 cites W2050673467 @default.
- W1990684267 cites W2050820996 @default.
- W1990684267 cites W2052413583 @default.
- W1990684267 cites W2053116546 @default.
- W1990684267 cites W2058355529 @default.
- W1990684267 cites W2060213036 @default.
- W1990684267 cites W2060811660 @default.
- W1990684267 cites W2060869545 @default.
- W1990684267 cites W2064061798 @default.
- W1990684267 cites W2065856736 @default.
- W1990684267 cites W2068211209 @default.
- W1990684267 cites W2073262551 @default.
- W1990684267 cites W2077391081 @default.
- W1990684267 cites W2078202075 @default.
- W1990684267 cites W2081761663 @default.
- W1990684267 cites W2083560373 @default.
- W1990684267 cites W2085501212 @default.
- W1990684267 cites W2090768811 @default.
- W1990684267 cites W2091101866 @default.
- W1990684267 cites W2091730472 @default.
- W1990684267 cites W2092646451 @default.
- W1990684267 cites W2100371320 @default.
- W1990684267 cites W2101258722 @default.
- W1990684267 cites W2108499492 @default.
- W1990684267 cites W2110302408 @default.
- W1990684267 cites W2114789306 @default.
- W1990684267 cites W2125564078 @default.
- W1990684267 cites W2126281717 @default.
- W1990684267 cites W2128572007 @default.
- W1990684267 cites W2131350133 @default.
- W1990684267 cites W2141070669 @default.
- W1990684267 cites W2145134025 @default.
- W1990684267 cites W2150336794 @default.
- W1990684267 cites W2186631003 @default.
- W1990684267 cites W2316417548 @default.
- W1990684267 cites W2330305831 @default.
- W1990684267 cites W2343785801 @default.
- W1990684267 cites W2570301454 @default.
- W1990684267 cites W2950420243 @default.
- W1990684267 cites W99274000 @default.
- W1990684267 doi "https://doi.org/10.1016/j.poly.2008.07.010" @default.
- W1990684267 hasPublicationYear "2008" @default.
- W1990684267 type Work @default.
- W1990684267 sameAs 1990684267 @default.
- W1990684267 citedByCount "19" @default.
- W1990684267 countsByYear W19906842672012 @default.
- W1990684267 countsByYear W19906842672013 @default.
- W1990684267 countsByYear W19906842672014 @default.
- W1990684267 countsByYear W19906842672015 @default.
- W1990684267 countsByYear W19906842672017 @default.
- W1990684267 countsByYear W19906842672018 @default.
- W1990684267 countsByYear W19906842672021 @default.
- W1990684267 crossrefType "journal-article" @default.
- W1990684267 hasAuthorship W1990684267A5013652065 @default.
- W1990684267 hasAuthorship W1990684267A5029233522 @default.
- W1990684267 hasAuthorship W1990684267A5058898558 @default.
- W1990684267 hasAuthorship W1990684267A5071729996 @default.