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- W1990687611 abstract "Abstract The syntheses, physical, spectroscopic characterizations and crystal structures of [Co(phen) 2 CO 3 ]ClO 3 , [Co(phen) 2 CO 3 ]BrO 3 ·3.5H 2 O and [Co(phen) 2 CO 3 ]IO 4 are described (phen = 1,10-phenanthroline, C 12 H 8 N 2 ). The crystal structures feature “synergistic” directional bonding interactions including cation-to-anion C–H⋯O(anion) bonds and anion-to-cation Cl⋯π and I–O⋯π bonds, as well as cation-to-cation C–H⋯O(carbonato) and π – π stacking interactions. The bromate structure also features distinctive O–H⋯O hydrogen bonding networks involving the water molecules. The facile formation of this series of complex salts with relatively small K sp values suggests that the [Co(phen) 2 CO 3 ] + complex ion may be effective as a binding agent for oxo-anions containing halogen atoms(halates) in an aqueous environment." @default.
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- W1990687611 date "2011-06-01" @default.
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- W1990687611 title "Synergistic cation-to-anion and anion-to-cation interactions in the binding of oxoanions: Syntheses, characterizations, and single-crystal structures of [Co(phen)2CO3]ClO3, [Co(phen)2CO3]BrO3·3.5H2O and [Co(phen)2CO3]IO4" @default.
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- W1990687611 doi "https://doi.org/10.1016/j.molstruc.2011.04.020" @default.
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