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- W1990693400 abstract "A method based on gas chromatography has been developed as a means of determining the MWD (Mn, MwandMw/Mn) of ethylene oligomers and the fractional composition of the disproportionation products of higher olefins. It is shown that oligomers obtainable by ethylene oligomerization on the system TiCl4C2H5AlCl2-modifier are C4C36 α-olefins with an even number of carbon atoms. These oligomers have a discrete-continuous most probable MWD (Schultz-Flory distribution). It has been established that the disproportionation of oct-1-ene on system WCl6Sn(n-C4H9)4 results in the formation of C3C13 olefins with even and uneven numbers of carbon atoms, along with tetradec-7-ene and ethylene. It is suggested that C3C13 olefin formation takes place as a result of the disproportionation of isomerized octenes." @default.
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- W1990693400 date "1977-01-01" @default.
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- W1990693400 title "Gas chromatographic determination of the molecular weight distribution of ethylene oligomers and of the fractional composition of the disproportionation products of higher olefins" @default.
- W1990693400 doi "https://doi.org/10.1016/0032-3950(77)90426-9" @default.
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