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• W1990707711 abstract "Abstract The association between acrylonitrile (CH 2 CHCN) and Ag + ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0 and 6.0 m silver ion (as silver nitrate). The wavenumber of the new band (2249 cm −1 , displaced about +20 cm −1 from the bulk solvent CN stretching) was independent of the concentration, although a small temperature effect was detected. The evolution of the associated acrylonitrile concentration with temperature suggests a flimsy solvation sphere. The experimental results are interpreted in dynamic terms, assuming a general equilibrium between positively and negatively solvated silver ions." @default.
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• W1990707711 date "1996-10-01" @default.
• W1990707711 modified "2023-09-24" @default.
• W1990707711 title "Raman spectroscopic study of silver nitrate solutions in acrylonitrile at different temperatures (238–343 K)" @default.
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• W1990707711 doi "https://doi.org/10.1016/0584-8539(96)01705-9" @default.
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