Matches in SemOpenAlex for { <https://semopenalex.org/work/W199071811> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W199071811 abstract "We demonstrate in this paper that ESDIAD (electron stimulated desorption ion angular distribution) can give detailed information about the dynamical behavior of chemisorbed species and about the intermolecular forces which modify the dynamical motions of these species. Traditionally, spectroscopic methods have been used to study the dynamical behavior of molecules in gases, liquids, and in the adsorbed layer. In studies of the adsorbed molecular rotors H2, HD, and D2, EELS has been used to observe transitions between essentially free rotational states present on Cu(100) [1]. For CO hydrogen-bonded to OH groups on SiO2 surfaces, rotational wings have been observed by IR [2]. Recently, the axial rotation of adsorbed methoxy species (CH3O) on Al2O3 surfaces has also been studied in detail by IR [3]. These spectroscopic methods detect transitions between librational/rotational levels, but do not give information about the directionality of the surface forces which determine the barrier for hindered rotational motion. To provide this type of geometrical information, the ESDIAD method, by virtue of its ability to image chemical bond directions, has been employed here to observe hindered rotation in a chemisorbed layer. In addition, the freezing of the rotational motion of adsorbed molecules through the action of intermolecular forces between neighbor molecules has been directly observed using ESDIAD." @default.
- W199071811 created "2016-06-24" @default.
- W199071811 creator A5016109256 @default.
- W199071811 creator A5040150200 @default.
- W199071811 creator A5053254425 @default.
- W199071811 creator A5054310142 @default.
- W199071811 creator A5066668918 @default.
- W199071811 date "1988-01-01" @default.
- W199071811 modified "2023-09-27" @default.
- W199071811 title "Observation of Molecular Rotors on Surfaces by ESDIAD: Studies of PF3 and NH3 Chemisorption on Ni Surfaces" @default.
- W199071811 cites W1966649289 @default.
- W199071811 cites W1970304846 @default.
- W199071811 cites W1982013132 @default.
- W199071811 cites W1988852495 @default.
- W199071811 cites W2024850664 @default.
- W199071811 cites W2057292054 @default.
- W199071811 cites W2061496654 @default.
- W199071811 cites W2063830792 @default.
- W199071811 cites W2065070114 @default.
- W199071811 cites W2065673551 @default.
- W199071811 cites W2091900073 @default.
- W199071811 cites W2092577007 @default.
- W199071811 cites W2093874517 @default.
- W199071811 cites W4254829702 @default.
- W199071811 doi "https://doi.org/10.1007/978-3-642-73728-2_13" @default.
- W199071811 hasPublicationYear "1988" @default.
- W199071811 type Work @default.
- W199071811 sameAs 199071811 @default.
- W199071811 citedByCount "0" @default.
- W199071811 crossrefType "book-chapter" @default.
- W199071811 hasAuthorship W199071811A5016109256 @default.
- W199071811 hasAuthorship W199071811A5040150200 @default.
- W199071811 hasAuthorship W199071811A5053254425 @default.
- W199071811 hasAuthorship W199071811A5054310142 @default.
- W199071811 hasAuthorship W199071811A5066668918 @default.
- W199071811 hasConcept C121332964 @default.
- W199071811 hasConcept C145148216 @default.
- W199071811 hasConcept C147789679 @default.
- W199071811 hasConcept C150394285 @default.
- W199071811 hasConcept C159467904 @default.
- W199071811 hasConcept C162711632 @default.
- W199071811 hasConcept C166950319 @default.
- W199071811 hasConcept C178790620 @default.
- W199071811 hasConcept C184779094 @default.
- W199071811 hasConcept C185592680 @default.
- W199071811 hasConcept C32909587 @default.
- W199071811 hasConcept C33790079 @default.
- W199071811 hasConcept C41999313 @default.
- W199071811 hasConcept C6342182 @default.
- W199071811 hasConcept C74650414 @default.
- W199071811 hasConceptScore W199071811C121332964 @default.
- W199071811 hasConceptScore W199071811C145148216 @default.
- W199071811 hasConceptScore W199071811C147789679 @default.
- W199071811 hasConceptScore W199071811C150394285 @default.
- W199071811 hasConceptScore W199071811C159467904 @default.
- W199071811 hasConceptScore W199071811C162711632 @default.
- W199071811 hasConceptScore W199071811C166950319 @default.
- W199071811 hasConceptScore W199071811C178790620 @default.
- W199071811 hasConceptScore W199071811C184779094 @default.
- W199071811 hasConceptScore W199071811C185592680 @default.
- W199071811 hasConceptScore W199071811C32909587 @default.
- W199071811 hasConceptScore W199071811C33790079 @default.
- W199071811 hasConceptScore W199071811C41999313 @default.
- W199071811 hasConceptScore W199071811C6342182 @default.
- W199071811 hasConceptScore W199071811C74650414 @default.
- W199071811 hasLocation W1990718111 @default.
- W199071811 hasOpenAccess W199071811 @default.
- W199071811 hasPrimaryLocation W1990718111 @default.
- W199071811 hasRelatedWork W1536370358 @default.
- W199071811 hasRelatedWork W179617497 @default.
- W199071811 hasRelatedWork W1959913869 @default.
- W199071811 hasRelatedWork W1979131622 @default.
- W199071811 hasRelatedWork W1983361734 @default.
- W199071811 hasRelatedWork W1995097551 @default.
- W199071811 hasRelatedWork W1995270802 @default.
- W199071811 hasRelatedWork W2022234017 @default.
- W199071811 hasRelatedWork W2030765897 @default.
- W199071811 hasRelatedWork W2033014123 @default.
- W199071811 hasRelatedWork W2043940085 @default.
- W199071811 hasRelatedWork W2049197145 @default.
- W199071811 hasRelatedWork W2081698897 @default.
- W199071811 hasRelatedWork W2088906243 @default.
- W199071811 hasRelatedWork W2110267067 @default.
- W199071811 hasRelatedWork W2152200770 @default.
- W199071811 hasRelatedWork W219345358 @default.
- W199071811 hasRelatedWork W2737632831 @default.
- W199071811 hasRelatedWork W3106338602 @default.
- W199071811 hasRelatedWork W3186452048 @default.
- W199071811 isParatext "false" @default.
- W199071811 isRetracted "false" @default.
- W199071811 magId "199071811" @default.
- W199071811 workType "book-chapter" @default.