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- W1990751406 abstract "Abstract The PbO–Al 2 O 3 system has been extensively studied in literature. In the present study, experimental work was conducted in which equilibria between phases were investigated under air between 600°C and 800°C by X-ray diffraction. Three intermediate compounds reported in literature were confirmed, which are PbAl 12 O 19 (1PbO:6Al 2 O 3 ), PbAl 2 O 4 (1:1) and Pb 2 Al 2 O 5 (2:1). Results support a widely accepted version of the phase diagram in which these compounds exist. On the basis of the results obtained in this study and data considered from literature, a thermodynamic modeling according to the Calphad approach was performed, where all intermediate phases were considered as stoichiometric compounds and where the liquid phase was described by a two-sublattice ionic liquid model. Good agreement has been obtained from thermodynamic optimization in comparison with experimental results." @default.
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- W1990751406 date "2015-08-07" @default.
- W1990751406 modified "2023-10-18" @default.
- W1990751406 title "Phase equilibria investigations and thermodynamic modeling of the PbO–Al<sub>2</sub>O<sub>3</sub> system" @default.
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- W1990751406 doi "https://doi.org/10.3139/146.111248" @default.
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