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- W1990756312 abstract "Abstract The reaction between iodine and 1,4,8,11-tetraazacyclotetradecane (TACTD) is studied photometrically in various solvents like CCl 4 , CHCl 3 , CH 2 Cl 2 and 1,2-dichloroethane. The results reveal that in each solvent the (TACTD):I 2 ratio is 1:2 and the iodine complex is formulated as (TACTD)I + ·I 3 − . The obtained values of the formation constant ( K ), extinction coefficient (e) and oscillator strength (ƒ) for the iodine complex are shown to be strongly dependent on the polarity of the solvent. A linear correlation is obtained between either (ƒ) or (e) and the dielectric constant ( D ) of the solvent. The important role of the solvent is mainly suggested to be due to the interaction of the ionic iodine complex with the solvent." @default.
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- W1990756312 date "1988-01-01" @default.
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- W1990756312 title "Electronic spectral studies and solvent effects on the reaction of iodine with 1,4,8,11-tetraazacyclotetradecane" @default.
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- W1990756312 doi "https://doi.org/10.1016/0584-8539(88)80169-7" @default.
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