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- W1990798984 abstract "A red wing in the absorption of H2O in the first continuum which extends beyond 200 nm is induced by the matrix. A threshold energy of 6.95 eV is found for the quantum efficiency of permanent dissociation of H2O into OH and H. This corresponds to an additional barrier of 1.8 eV due to the matrix cage. The barrier is attributed to the sum of repulsive H–Ar pair potentials in an interstitial site of D3 symmetry, which has to be surmounted by the H atom on the way from the initial substitutional H2O site to the final stable Oh site of the abstracted H atom." @default.
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- W1990798984 date "1989-10-01" @default.
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- W1990798984 title "Cage effect for the abstraction of H from H2O in Ar matrices" @default.
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- W1990798984 doi "https://doi.org/10.1063/1.456842" @default.
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