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- W1990852487 abstract "The interaction of in-situ evaporated KOH with the basal plane of highly oriented pyrolytic graphite was investigated using UPS, AES and LEED from 30 to 600°C and multilayer to submonolayer coverage. The monolayer is more thermally stable than the multilayer. He II UPS results in the monolayer regime show emission from the potassium 3p level and the 3σ and 1π levels associated with the hydroxyl. Heating in vacuum decreases the intensity of these features concomitant with decreases in the potassium and oxygen AES signals. A constant oxygen-to-potassium stoichiometry is observed independent of coverage under UHV conditions. These results indicate reversible adsorption of KOH and maintenance of the OH bond in the adsorbed state. Adsorbed KOH causes a uniform shift in initial and final state graphite UPS features, which implies electron transference to the graphite due to the adsorbed salt. The presence of H2O or O2 in the residual gas increases the oxygen content in the adsorbed layer and decreases the shifts in graphite UPS features." @default.
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- W1990852487 date "1983-10-01" @default.
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- W1990852487 title "The interaction of KOH with the basal surface of graphite" @default.
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- W1990852487 doi "https://doi.org/10.1016/0039-6028(83)90484-3" @default.
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