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- W1990878974 abstract "Two novel coordination polymers of Co(II) with dicyanamide (dca) were obtained by the addition of ancillary ligands of pyrazine dioxide (pzdo) and 2-methyl pyrazine dioxide (mpdo) into the Co-dca binary system, respectively. Co[N(CN)(2)](2)(pzdo) (1) crystallizes in the orthorhombic space group of Pnnm (No. 58) with a = 9.4699(5) A, b = 14.9984(3) A, c = 7.4313(7) A, and Z = 4, while Co[N(CN)(2)](2)(mpdo) (2) is in the monoclinic space group C2 (No. 5) with a = 16.5391(4) A, b = 9.6065(2) A, c = 7.5001(2) A, beta = 105.779(1) degrees, and Z = 4. Both complexes contain similar two-dimensional triangular Co-dca layers, which offer rare examples of mixed 1,5-mu- and mu(3)-dca bridging coordination polymers with long-range ferromagnetic ordering below ca. 2.5 K." @default.
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- W1990878974 date "2003-07-25" @default.
- W1990878974 modified "2023-09-30" @default.
- W1990878974 title "Long-Range Ferromagnetic Ordering in Two-Dimensional Coordination Polymers Co[N(CN)<sub>2</sub>]<sub>2</sub>(L) [L = Pyrazine Dioxide (pzdo) and 2-Methyl Pyrazine Dioxide (mpdo)] with Dual μ- and μ<sub>3</sub>-[N(CN)<sub>2</sub>] Bridges" @default.
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- W1990878974 doi "https://doi.org/10.1021/ic034202i" @default.
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