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• W1990883640 abstract "The reactions of aqueous solutions of the tetrahedral cluster anions [Re4Q4(CN)12]4− (Q = S, Se) with lanthanide chlorides resulted in the crystallization of the formed compounds into two main structural types [{Ln(H2O)4(H2O)2/3Cl1/3}3{Re4Q4(CN)12}2]·2H2O (Ln = La–Gd, Q = S, Se) and K0.5(H)0.5[{Ln(H2O)4}{Re4S4(CN)12}]·nH2O or (H)[{Ln(H2O)4}{Re4Se4(CN)12}]·nH2O (Ln = Tb–Lu). Compounds of the first type crystallize in the hexagonal crystal system (space group Р63/m) and they have a three-dimensional polymeric structure; compounds of the second type crystallize in the orthorhombic crystal system (space group Cmcm) and they have a two-dimensional crystal structure due to the polymeric anion {[{Ln(H2O)4}{Re4Q4(CN)12}]−}∞∞." @default.
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• W1990883640 date "2011-05-01" @default.
• W1990883640 modified "2023-09-26" @default.
• W1990883640 title "Two types of coordination polymers based on cluster anions [Re4Q4(CN)12]4− (Q=S, Se) and cations of rare-earth metals Ln3+: Syntheses and crystal structures" @default.
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• W1990883640 doi "https://doi.org/10.1016/j.poly.2011.02.051" @default.
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