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- W1990893700 abstract "A mixed alkali metal titanate of composition AxTi2-x/3Lix/3O4 (A = K, Rb, Cs) has been prepared and its ion-exchange/intercalation properties have been explored. Solid-state calcination of appropriate mixtures of TiO2 and alkali metal carbonates produced the titanate at a stoichiometry of x = 0.80 for A = K, 0.75 for Rb, and 0.70 for Cs. Rietveld refinement on neutron diffraction data confirmed that the orthorhombic structure is comprised of lepidocrocite-related host layers of Ti2-x/3Lix/3O4 and charge-balancing A ions in the interlayer domain. Complete extraction of both alkali metal ions was achieved by acid-leaching, producing a new protonic titanate of H4x/3Ti2-x/3O4·H2O. This phase is distinguished from isomorphous related compounds in terms of high proton content as a consequence of exchangeable Li ions located in the host framework. The material took up alkali metal ions and organoammonium ions from aqueous media. These ion-exchange and intercalation reactions brought about expansion/contraction of the gallery height and lateral displacement of the layers. The resulting various types of layer sequence can be understood in terms of the nature of the interlayer species." @default.
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- W1990893700 date "1998-11-17" @default.
- W1990893700 modified "2023-10-11" @default.
- W1990893700 title "A Mixed Alkali Metal Titanate with the Lepidocrocite-like Layered Structure. Preparation, Crystal Structure, Protonic Form, and Acid−Base Intercalation Properties" @default.
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- W1990893700 doi "https://doi.org/10.1021/cm980535f" @default.
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