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- W1990896360 abstract "Abstract Variation of the forbidden gap of SbSI crystals in the phase transition region is analyzed on the basis of calculations using the empirical pseudopotential method for the paraelectric (PEP) and ferroelectric phase (FEP). Other theoretical SbSI studies are critically reviewed. The band gap at several special points of the Brillouin zone and some characteristic parameters of the band structure are considered. At the ferroelectric phase transition, the variation of the direct and indirect gaps is mainly determined by variation of coupling between 3p-orbitals of S and 5p-orbitals of Sb. During the phase transition, the most significant changes are observed with the valence band top at points Q, C, R, H, E and with the conduction band bottom at points H, T and E of the Brillouin zone." @default.
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- W1990896360 date "1998-04-01" @default.
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- W1990896360 title "Variation of the SbSI crystal energy gap at phase transition" @default.
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- W1990896360 doi "https://doi.org/10.1080/00150199808018066" @default.
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