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- W1990967939 abstract "A novel phenoxo-bridged dinuclear CoII complex with a diazamesocyclic ligand bearing one additional phenol functional donor group, [CoLCl]2·2C3H6O (1) (where HL=1-(2-hydroxybenzyl)-1,5-diazacyclooctane), has been synthesized and characterized by elemental analyses, conductance, thermal analyses, IR and UV–vis spectra. The crystal structure of complex 1 has been determined by X-ray diffraction technique, which reveals that it is a neutral complex and resides on a crystallographic inversion center. The two CoII centers bridged by the phenoxo groups are penta-coordinated, taking a coordination sphere in the midst of the ideal square-pyramid and trigonal bipyramid. 1,5-Diazacyclooctane of the ligand takes a boat/chair conformation and an H atom from it effectively blocks the axial coordination site opposite the Cl− ligand to form CoN2O2Cl geometry. The crystal structure is stabilized by the N–H⋯O hydrogen bond between the amino group and the acetone molecule." @default.
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- W1990967939 date "2002-11-01" @default.
- W1990967939 modified "2023-09-29" @default.
- W1990967939 title "Synthesis, spectral and structural characterization of a novel phenoxo-bridged dinuclear CoII complex with a tridentate phenol-functionalized diazamesocyclic ligand" @default.
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- W1990967939 doi "https://doi.org/10.1016/s0022-2860(02)00321-6" @default.
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