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• W1990969909 abstract "A Tosflex/mercury film electrode (TMFE) was prepared by spin-coating a solution of the perfluorinated anion exchange polymer Tosflex onto a glassy carbon electrode surface followed by electrodeposition of a mercury film on this electrode. This electrode was used for the determination of trace thallium(III) which was preconcentrated onto the TMFE as the [TlCl4]− anion in a chloride medium by the anion-exchange feature of Tosflex and then determined by anodic square-wave stripping voltammetry (SWSV). Various parameters influencing the determination of thallium(III) were examined in detail. With 1 min accumulation, the analytical signal versus concentration dependence was linear from 0 to 80 ppb, and the detection limit was 0.1 ppb. The modified electrode showed good resistance to interferences from surface-active compounds and common ions. For repetitive use, the TMFE surface could be easily regenerated by setting the electrode potential at −0.4 V for 30 s." @default.
• W1990969909 created "2016-06-24" @default.
• W1990969909 creator A5048348379 @default.
• W1990969909 creator A5061734673 @default.
• W1990969909 date "1998-10-01" @default.
• W1990969909 modified "2023-09-23" @default.
• W1990969909 title "Anodic Stripping Voltammetric Determination of Thallium(III) Using a Tosflex/Mercury Film Electrode" @default.
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• W1990969909 doi "https://doi.org/10.1002/(sici)1521-4109(199810)10:15<1052::aid-elan1052>3.0.co;2-z" @default.
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