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• W1990971572 abstract "Treatment of the molybdenum dimethylamido compounds, Mo(NMe2)4 and Mo2(NMe2)6 (MoMo), with 2-phenylphenol (HOAr-2Ph), leads to formation of the aryloxide compounds, Mo(OAr-2Ph)4(HNMe2)2 (1) and Mo2(OAr-2Ph)6(HNMe2)2 (2), respectively. A single crystal X-ray diffraction analysis of 1 shows a trans arrangement of dimethylamine ligands about the octahedral MoO4N2 core, while in 2 an unbridged O3NMoMoNO3 central coordination environment is present. Spectroscopic studies on 2 indicate a significant barrier to rotation about the unbridged molybdenum-molybdenum triple bond, presumably due to the steric demands of the OAr-2Ph ligands. Crystal data for MoO4N2C52H50 (1) at 21°C: a = 9.617(6), b = 10.199(1), c = 12.315(7) Å, α = 107.04(2), β = 106.29(5), γ = 95.46(2)δ, Z = 1, dcalc = 1.317 g cm−3 in space group P1̄ ; for Mo2O6N2C83H70 (2) at 19°C: a = 22.890(2), b = 13.854(4), c = 24.337(2) Å, β = 113.969(8)°, Z = 4, dcalc = 1.303 g cm−3 in space group P21/c." @default.
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• W1990971572 date "1989-01-01" @default.
• W1990971572 modified "2023-10-16" @default.
• W1990971572 title "Synthesis, structure and spectroscopic properties of some 2-phenylphenoxide derivatives of molybdenum" @default.
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• W1990971572 doi "https://doi.org/10.1016/s0277-5387(00)86423-2" @default.
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