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- W1990994057 abstract "The morphology of the hetero-epitaxy of menthol on carbon, fuzed quartz and glass substrates is investigated for inert gas transport vapor deposition. Substrate temperatures of 22–24°C are utilized, some 19°C less than the melting temperature of menthol. Formation of an intermediate lifetime liquid menthol drop state is observed, which has a significant effect on deposit growth morphology. It is suggested that liquid supercooling, latent heat of condensation and low thermal conductivity to the substrate all contribute to maintenance of the liquid state with connective turbulence causing fluctuations in instantaneous heat of condensation input to menthol nuclei by modulating local flux rates. Formation of the observed intermediate liquid stage tends to decrease initial sticking coefficient and results in deposit growth by menthol crystallite stacking, branching and network formation. A related morphological growth mechanism was first discussed by Wagner and Ellis for whisker development in the vapor-liquid-solid deposition of silicon. There are significant differences in the mechanisms and parameters important to the actual formation of the liquid state, however, and consequently the growth morphology for menthol is much more complex." @default.
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- W1990994057 title "Vapor phase nucleation and growth of menthol on carbon, glass and fuzed quartz substrates" @default.
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- W1990994057 doi "https://doi.org/10.1016/0022-0248(76)90218-9" @default.
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