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- W1991008977 abstract "Komplexe cis-M(CO)4(L)SO2 (M = Cr, Mo, W;L = CO, P(CH3)3), P(C6H5)2CH3, P(OCH3)3) und mer-M(CO)3(C6H5)2PC2H4P(C6H5)2SO2 (M = Cr, Mo, W) mit η1-planar gebundenem Schwefeldioxid werden beschrieben. η2-Koordiniertes Schwefeldioxid liegt in fac-Mo(CO)3-(C6H5)2PC2H4P(C6H5)2SO2 vor. Die protonenkatalysierte fac-mer-Isomerisierung dieses Derivates ist das erste Beispiel für eine nur durch änderung der Geometrie am Metall hervorgerufene Bindungsisomerisierung an einem Schwefeldioxid-Komplex. Das koordinierte Schwefeldioxid wird von Lewis-Basen leicht substituiert. Sulfur(IV) Compounds as Ligands, 1. Carbonyl Chromium, Molybdenum, and Tungsten Complexes of Sulfur Dioxide Complexes cis-M(CO)4(L)SO2(M = Cr, Mo, W;L = CO, P(CH3)3), P(C6H5)2CH3, P(OCH3)3) and mer-M(CO)3(C6H5)2PC2H4P(C6H5)2SO2 (M = Cr, Mo, W) containing η1-planar coordinated sulfur dioxide are described. η2 Coordination of sulfur dioxide is found in fac-Mo(CO)3-(C6H5)2PC2H4P(C6H5)2SO2. The proton catalyzed fac-mer isomerization of this derivative is the first example of linkage isomerization of sulfur dioxide caused by a change of the coordination geometry around the metal. The coordinated sulfur dioxide is readily displaced by Lewis bases." @default.
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- W1991008977 date "1982-07-01" @default.
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- W1991008977 title "Schwefel(IV)‐Verbindungen als Liganden, 1. Carbonyl‐Chrom‐, Molybdän‐ und Wolfram‐Komplexe des Schwefeldioxids" @default.
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- W1991008977 doi "https://doi.org/10.1002/cber.19821150724" @default.
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