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- W1991176314 abstract "We study the equilibrium morphology of droplets of symmetric AB diblock copolymer on a flat substrate. Using self-consistent field theory (SCFT), we provide the first predictions for the equilibrium droplet shape and its internal structure. When the substrate affinity for the A component, ηA, is small, the droplet adopts a nearly spherical shape much like that of simple fluids. Inside the spherical droplet, however, concentric circular lamellar layers stack on top of each other; hence the thickness of the droplet is effectively quantized by a half-integer or integer number of layers. At larger ηA and smaller contact angle, the area of the upper-most layer becomes relatively large, resulting in a nearly flat, faceted top surface, followed by a semi-spherical slope. This geometry is remarkably reminiscent of the droplet shapes observed with smectic liquid crystals." @default.
- W1991176314 created "2016-06-24" @default.
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- W1991176314 date "2009-01-01" @default.
- W1991176314 modified "2023-10-01" @default.
- W1991176314 title "Droplets of structured fluid on a flat substrate" @default.
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- W1991176314 doi "https://doi.org/10.1039/b905163e" @default.
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