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- W1991215246 abstract "It is shown that the adduct of Rh2(CF3COO)4 with NBD is formed in dichloromethane at room temperature. The addition of an NBD excess to the Rh2(CF3COO)4 solution results in the reduction of Rh(II) to Rh(I). Heating of Rh2(CF3COO)4 either in NBD or in its mixture with benzene (1:3) yields red crystals of [Rh(NBD)CF3COO]2. This compound is the catalyst of NBD cyclodimerization. The selectivity of cyclodimer formation is regulated by the ligand environment of the rhodium atom." @default.
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- W1991215246 date "1987-04-01" @default.
- W1991215246 modified "2023-10-16" @default.
- W1991215246 title "Cyclodimerization of bicyclo [2.2.1]hepta-2,5-diene by rhodium carboxylates" @default.
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- W1991215246 doi "https://doi.org/10.1016/0304-5102(87)80006-8" @default.
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