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- W1991231445 abstract "The CaII ion of the title complex, [Cu(SCN)(C8H20N4)]2[Ca(NCS)4(H2O)2].2H2O, is situated at an inversion center. The coordination geometry around the CuII ion is a symmetrical square pyramid with the tetraamine N atoms equatorial and thiocyanato S atom axial. The four donor N atoms of the macrocyclic ligand form a buckled plane, the CuII ion lies 0.553 (1) Å out of this plane towards the thiocyanato group. The hydrogen bonds between water molecules and thiocyanato groups help stabilize the crystal structure. A water molecule binds the CuII complex and the CaII complex together through hydrogen bonds." @default.
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- W1991231445 date "1997-11-15" @default.
- W1991231445 modified "2023-10-07" @default.
- W1991231445 title "Bis[(1,4,7,10-tetraazacyclododecane-κ<sup>4</sup><i>N</i>)(thiocyanato-<i>S</i>)copper(II)] Diaquatetrakis(isothiocyanato-<i>N</i>)calcate(2–) Dihydrate" @default.
- W1991231445 doi "https://doi.org/10.1107/s0108270197008639" @default.
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