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- W1991231640 abstract "Abstract The synthesis and characterization of the cluster [Bu 4 N] 3 [Nb 6 Cl 12 (OSO 2 CF 3 ) 6 ] is reported, and the metathesis of this cluster with [Bu 4 N]X resulted in the formation of the clusters [Bu 4 N] n [Nb 6 Cl 12 X 6 ] (X=Cl − , Br − , I − and SCN − ; n =3 or 4). The cluster [Bu 4 N] 3 [Nb 6 Cl 12 (OSO 2 CF 3 ) 6 ] crystallizes in the monoclinic space group C 2/ c (no. 15) with a =26.808(4), b =25.826(6), c =15.889(4) A, β =91.96(2)°, V =10994(3) A 3 , and Z =4. A refinement was based on 4105 ( I >3.00 σ ( I )) observed reflections with 436 variable parameters had agreement parameters of R =0.087 and R w =0.109. The structure consists of a slightly distorted metal octahedron surrounded by 12 edge-bridging chlorine atoms and six axial OSO 2 CF 3 − groups. The average NbNb bond length is 2.947 A, the average NbCl bond length is 2.429 A, and the average NbO bond length is 2.15 A. Vibrational and electronic spectra provide a means for monitoring the facile reaction chemistry of [Bu 4 N] 3 [Nb 6 Cl 12 (OSO 2 CF 3 ) 6 ]." @default.
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- W1991231640 date "2000-04-01" @default.
- W1991231640 modified "2023-09-24" @default.
- W1991231640 title "Synthesis and structure of the useful starting material [Bu4N]3[Nb6Cl12(OSO2CF3)6]" @default.
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- W1991231640 doi "https://doi.org/10.1016/s0020-1693(00)00028-1" @default.
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