Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991232290> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W1991232290 endingPage "279" @default.
- W1991232290 startingPage "273" @default.
- W1991232290 abstract "Purpose Polymer networks with adjustable properties prepared from endgroup-functionalized oligoesters by UV-crosslinking in melt have evolved into versatile multifunctional biomaterials. In addition to the molecular weight or architecture of precursors, the reaction conditions for crosslinking are pivotal for the polymer network properties. Crosslinking of precursors in solution may facilitate low-temperature processes and are compared here to networks synthesized in melt. Methods Oligo(∊-caprolactone)-(z)methacrylate (oCL-(z)IEMA) precursors with a linear (z = di) or a four-armed star-shaped (z = tetra) architecture were crosslinked by radical polymerization in melt or in solution with UV irradiation. The thermal, mechanical, and swelling properties of the polymer networks obtained were characterized. Results Crosslinking in solution resulted in materials with lower Young's moduli (E), lower maximum stress (σ max ), and higher elongation at break (∊ B ) as determined at 70 °C. Polymer networks from 8 kDa star-shaped precursors exhibited poor elasticity when synthesized in the melt, but can be established as stretchable materials with a semi-crystalline morphology, a high gel- content, and a high elongation at break when prepared in solution. Conclusions The crosslinking condition of methacrylate functionalized precursors significantly affected network properties. For some types of precursors such as star-shaped telechelics, synthesis in solution provided semi-crystalline elastic materials that were not accessible from crosslinking in melt." @default.
- W1991232290 created "2016-06-24" @default.
- W1991232290 creator A5037426480 @default.
- W1991232290 creator A5042215304 @default.
- W1991232290 creator A5063227740 @default.
- W1991232290 creator A5088043774 @default.
- W1991232290 date "2012-09-01" @default.
- W1991232290 modified "2023-10-16" @default.
- W1991232290 title "Oligo(∊-caprolactone)-Based Polymer Networks Prepared by Photocrosslinking in Solution" @default.
- W1991232290 cites W1602472127 @default.
- W1991232290 cites W1984080313 @default.
- W1991232290 cites W1995645236 @default.
- W1991232290 cites W2003102279 @default.
- W1991232290 cites W2012190115 @default.
- W1991232290 cites W2022946671 @default.
- W1991232290 cites W2034935424 @default.
- W1991232290 cites W2041031326 @default.
- W1991232290 cites W2048401675 @default.
- W1991232290 cites W2055471521 @default.
- W1991232290 cites W2056673763 @default.
- W1991232290 cites W2089554484 @default.
- W1991232290 cites W2145421363 @default.
- W1991232290 cites W2146789927 @default.
- W1991232290 cites W2157976579 @default.
- W1991232290 cites W2167460815 @default.
- W1991232290 cites W2315232123 @default.
- W1991232290 doi "https://doi.org/10.5301/jabfm.2012.10372" @default.
- W1991232290 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23242870" @default.
- W1991232290 hasPublicationYear "2012" @default.
- W1991232290 type Work @default.
- W1991232290 sameAs 1991232290 @default.
- W1991232290 citedByCount "1" @default.
- W1991232290 countsByYear W19912322902013 @default.
- W1991232290 crossrefType "journal-article" @default.
- W1991232290 hasAuthorship W1991232290A5037426480 @default.
- W1991232290 hasAuthorship W1991232290A5042215304 @default.
- W1991232290 hasAuthorship W1991232290A5063227740 @default.
- W1991232290 hasAuthorship W1991232290A5088043774 @default.
- W1991232290 hasBestOaLocation W19912322901 @default.
- W1991232290 hasConcept C119394753 @default.
- W1991232290 hasConcept C127413603 @default.
- W1991232290 hasConcept C132050475 @default.
- W1991232290 hasConcept C15920480 @default.
- W1991232290 hasConcept C159985019 @default.
- W1991232290 hasConcept C188027245 @default.
- W1991232290 hasConcept C192562407 @default.
- W1991232290 hasConcept C2781111393 @default.
- W1991232290 hasConcept C42360764 @default.
- W1991232290 hasConcept C44228677 @default.
- W1991232290 hasConcept C521977710 @default.
- W1991232290 hasConceptScore W1991232290C119394753 @default.
- W1991232290 hasConceptScore W1991232290C127413603 @default.
- W1991232290 hasConceptScore W1991232290C132050475 @default.
- W1991232290 hasConceptScore W1991232290C15920480 @default.
- W1991232290 hasConceptScore W1991232290C159985019 @default.
- W1991232290 hasConceptScore W1991232290C188027245 @default.
- W1991232290 hasConceptScore W1991232290C192562407 @default.
- W1991232290 hasConceptScore W1991232290C2781111393 @default.
- W1991232290 hasConceptScore W1991232290C42360764 @default.
- W1991232290 hasConceptScore W1991232290C44228677 @default.
- W1991232290 hasConceptScore W1991232290C521977710 @default.
- W1991232290 hasIssue "3" @default.
- W1991232290 hasLocation W19912322901 @default.
- W1991232290 hasLocation W19912322902 @default.
- W1991232290 hasOpenAccess W1991232290 @default.
- W1991232290 hasPrimaryLocation W19912322901 @default.
- W1991232290 hasRelatedWork W1521524204 @default.
- W1991232290 hasRelatedWork W1533289191 @default.
- W1991232290 hasRelatedWork W1970111938 @default.
- W1991232290 hasRelatedWork W1996393783 @default.
- W1991232290 hasRelatedWork W2016205995 @default.
- W1991232290 hasRelatedWork W2157663430 @default.
- W1991232290 hasRelatedWork W2240722815 @default.
- W1991232290 hasRelatedWork W2348858995 @default.
- W1991232290 hasRelatedWork W2368812931 @default.
- W1991232290 hasRelatedWork W4365813959 @default.
- W1991232290 hasVolume "10" @default.
- W1991232290 isParatext "false" @default.
- W1991232290 isRetracted "false" @default.
- W1991232290 magId "1991232290" @default.
- W1991232290 workType "article" @default.