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- W1991235047 abstract "The adsorption isotherms of several polar and non-polar compounds on active carbons with modified surfaces were determined chromatographically at different temperatures. The results were compared with those obtained by the static method. The entropies and heats of adsorption were calculated from the adsorption isotherms and compared with the values obtained from calorimetric measurements. The results were closest for adsorbents with a weakly developed microporous structure. The effect of the carrier gas flow-rate through the adsorbent bed in the column on the shape of the chromatographically determined adsorption isotherm was tested. The linear forms of equations corresponding to the BET, Hüttig, Kiselev and Hill physical adsorption models were used. The adsorption isotherms of aliphatic alcohols chromatographically were best described in terms of the Hill model." @default.
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- W1991235047 date "1991-09-01" @default.
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- W1991235047 title "Chromatographic determination of the physico-chemical parameters of adsorption on active carbons" @default.
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- W1991235047 doi "https://doi.org/10.1016/s0021-9673(01)96241-7" @default.
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