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- W1991238759 abstract "Die Trimethyle des Al, Ga und In reagieren mit äquimolaren Mengen an Phosphor- und Phosphinsäureamiden HN(Me)P(Y)X2 (mit Y = O, S und X = F, Cl, Me) unter Bildung von dimeren oder monomeren Dimethylmetallderivaten dieser Säuren. Die Schwingungs-spektren der Verbindungen werden diskutiert. Nach Aussage der 1H-NMR-Spektren liegen die di-meren Al-Verbindungen Me2AlOPN(Me)Me2 und Me2ALSPN(Me)Me2 als Gemische zweier Struktur-isomerer vor. Studies on Dialkyl Metal Phosphoric and Phosphinic Acid Derivatives of the Elements Aluminium, Gallium, Indium, and Thallium. V. Preparation and Spectroscopic Investigations of the Dimethyl Metal N-methyl Dihalogeno-phosphoric Acid, Dimethyl Phosphinic Acid and Dimethyl Thiophosphinic Acid Amides, respectively The trimethyl compounds of Al, Ga, and In react with equimolar quantities of phosphoric or phosphinic acid amides HN(Me)P(Y)X2 (Y = O, S) and X = F, Cl, Me to form dimeric or monomeric dimethyl metal derivatives of these acids. The vibrational spectra of these compounds are discussed. The 1H-NMR spectra of the dimeric Al compounds MeAlOPN(Me)Me2 and Me2ALSPN(Me)Me2 show the presence of two structural isomers." @default.
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- W1991238759 date "1980-06-01" @default.
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- W1991238759 title "Untersuchungen an Dialkylmetallphosphor- und phosphins�urederivaten der Elemente Aluminium, Gallium, Indium und Thallium. V. Darstellung und spektroskopische Untersuchung der Dimethyl-metall-N-methyl-dihalogenophosphors�ure- bzw. -dimethyl-phosphin- und -dimethylthiophosphins�ureamide" @default.
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- W1991238759 doi "https://doi.org/10.1002/zaac.19804650111" @default.
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