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- W1991252008 abstract "The hindered rotation in cubic fields of various shapes and intensities is studied. The “Devonshire Model” is extended to include cubic fields being linear combinations of spherical harmonics of order four and six. In contrast to Devonshire's potential, this two parameter manifold of potentials contains some with the energy minima at the 〈110〉 directions. Agreement is found between the low-lying rotator levels in a large hindering potential and these of harmonic oscillators localized in the minimum wells of the potential. Ein Rotator wird untersucht, der durch verschiedene Felder kubischer Symmetrie behindert wird. Das „Devonshire Modell”︁ wird erweitert, indem kubische Felder betrachtet werden, die Linearkombinationen von Kugelfunktionen vierter und sechster Ordnung sind. Im Gegensatz zum „Devonshire Modell”︁ enthält diese zweiparametrige Menge von Feldern auch solche, deren Minima in den 〈110〉-Richtungen liegen. Für hohe Hinderungspotentiale stimmen die tiefenergetischen Zustände des Rotators mit denen von harmonischen Oszillatoren, lokalisiert in den Minima des Potentials, überein." @default.
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- W1991252008 date "1972-08-01" @default.
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- W1991252008 title "The Hindered Rotation in Various Fields of Cubic Symmetry" @default.
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- W1991252008 doi "https://doi.org/10.1002/pssb.2220520210" @default.
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