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- W1991275302 abstract "Due to the coordinative nature of NH3 in the LiBH4 ammines, NH3 desorbs predominantly at temperatures below 180 °C under an open flow mode. Interestingly, the emission of NH3 can be effectively suppressed in conjunction with improved hydrogen desorption properties by introducing a cobalt catalyst (Co-catalyst) and heating the amines in a small closed vessel. Under such condition, Li(NH3)nBH4, where n = 1, 4/3, 2, releases ca. 15.3 wt%, 17.8 wt%, 14.3 wt% hydrogen at 250 °C, respectively. Fairly high H-purity (99.99%) can be achieved in the Co-catalyzed Li(NH3)BH4 sample upon releasing over 15 wt% H2 below 250 °C. As for the Co-catalyzed Li(NH3)2BH4 sample approximately 14.3 wt% of H2 (H-purity: 97.60%) can be desorbed in a much improved reaction rate." @default.
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- W1991275302 date "2015-04-01" @default.
- W1991275302 modified "2023-09-26" @default.
- W1991275302 title "The effect of NH3 content on hydrogen release from LiBH4–NH3 system" @default.
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- W1991275302 doi "https://doi.org/10.1016/j.ijhydene.2015.01.134" @default.
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