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- W1991309393 abstract "Abstract The hydrogen sorption kinetics properties of MgH 2 based composites obtained by mechanical milling were investigated. The composites analyzed in this paper were MgH 2 ball milled with 5 wt.% of NbCl 3 , NbCl 5 and ZrCl 4 chlorides. The samples were investigated using X-ray diffraction, XRD, differential scanning calorimetry, DSC and hydrogen absorption and desorption kinetics tests at 300 and 350 °C. DSC curves showed that the hydrogen desorption peak temperature of all samples milled with catalyst was lower when compared to MgH 2 milled without catalyst. The NbCl 5 catalyzed MgH 2 showed the faster absorption kinetics attaining a total hydrogen capacity of 6 wt.% in 6 min at 300 °C and the sample containing NbCl 3 showed the faster desorption kinetics, desorbing 5.5 wt.% of H 2 in 10 min at 300 °C." @default.
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- W1991309393 date "2014-12-01" @default.
- W1991309393 modified "2023-09-26" @default.
- W1991309393 title "Catalytic effect of chlorides compounds on hydrogen sorption properties of magnesium hydride" @default.
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- W1991309393 doi "https://doi.org/10.1016/j.jallcom.2014.02.074" @default.
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