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- W1991314193 abstract "In the unsymmetrized self-consistent field approximation the second-order correction to the Helmholtz free energy is derived by statistical perturbation theory. This correction takes into account the effect of the anharn micity of odd orders on the Helmholtz free energy and on the thermodynamic properties of a crystal. The case of the linear chain is studied in more detail. Special attention is paid to the case of strong anharmonicity. In der Näherung des unsymmetrisierten, selbstkonsistenten Feldes werden die Korrekturen zweiter Ordnung zur Helmholtzschen freien Energie mit statistischer Störungstheorie abgeleitet. Diese Korrektur berücksichtigt den Einfluß der Anharmonizität ungerader Ordnung auf die Helmholtzsche freie Energie und die thermodynamischen Eigenschaften eines Kristalls. Besonders ausführlich wird der Fall starker Anharmonizität betrachtet." @default.
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- W1991314193 date "1975-11-01" @default.
- W1991314193 modified "2023-09-25" @default.
- W1991314193 title "Unsymmetrized self-consistent field approximation for a crystal. I. Linear chain" @default.
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- W1991314193 doi "https://doi.org/10.1002/pssb.2220720106" @default.
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