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• W1991317512 abstract "The radical pair model of chemically induced dynamic electron polarization (CIDEP) is experimentally verified. Aqueous solutions of alcohols were irradiated with 3 MeV electrons and observed with time resolved electron paramagnetic resonance (EPR) spectroscopy. Relative line intensities of the polarized EPR spectra of radicals from methanol and especially ethylene glycol, alone and in the presence of radicals from compounds containing halogens, illustrates the polarization dependence on the g‐factor differences between the radical pair components. The observation of the relative polarization enhancement in the various lines of the multiline EPR spectra illustrates the polarization dependence on the hyperfine terms. Intrinsic enhancements are calculated and are shown to be proportional to the observed enhancement, showing that the radical pair model of CIDEP is qualitatively correct." @default.
• W1991317512 created "2016-06-24" @default.
• W1991317512 creator A5081322051 @default.
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• W1991317512 date "1975-06-15" @default.
• W1991317512 modified "2023-09-26" @default.
• W1991317512 title "Chemically induced dynamic electron polarization. Pulse radiolysis of aqueous solutions of alcohols" @default.
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• W1991317512 doi "https://doi.org/10.1063/1.430401" @default.
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