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- W1991322365 abstract "Previous data by other writers who infer the existence of aluminum suboxides in the solid state are critically discussed and alternatively interpreted. High‐temperature X‐ray diffraction patterns previously attributed to crystalline Al 2 O and AlO are identified as those of Al 4 C 3 and AlTaO 2 , respectively. The melting curve observed by Baur and Brunner, suggesting the existence of a compound of the approximate composition Al 2 O 9 , corresponds to the pseudobinary system Al 2 O 3 −Al 4 C 3 . The T‐x melting curve of the system Al 2 O 3 −Al was determined. There is no indication of the existence of crystalline aluminum suboxide, the only condensed phases being α‐Al 2 O 3 and Al. The liquidus indicates demixing of liquid Al and molten Al 2 O 3 . There is very limited intersolubility, and the addition of Al does not lower the melting point of Al 2 O 3 measurably. With these facts and some additional information from the literature about the gaseous species, the P‐T‐x diagram of the system Al‐O was constructed." @default.
- W1991322365 created "2016-06-24" @default.
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- W1991322365 date "1968-12-01" @default.
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- W1991322365 title "The System Al-O" @default.
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- W1991322365 doi "https://doi.org/10.1111/j.1151-2916.1968.tb15931.x" @default.
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