FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991346145> ?p ?o ?g. }

• W1991346145 endingPage "4637" @default.
• W1991346145 startingPage "4630" @default.
• W1991346145 abstract "We report the design and synthesis of an amide functionalized microporous organic polymer (Am-MOP) prepared from trimesic acid and p-phenylenediamine using thionyl chloride as a reagent. Polar amide (-CONH-) functional groups act as a linking unit between the node and spacer and constitute the pore wall of the continuous polymeric network. The strong covalent bonds between the building blocks (trimesic acid and p-phenylenediamine) through amide bond linkages provide high thermal and chemical stability to Am-MOP. The presence of a highly polar pore surface allows selective CO2 uptake at 195 K over other gases such as N2, Ar, and O2. The CO2 molecule interacts with amide functional groups via Lewis acid-base type interactions as demonstrated through DFT calculations. Furthermore, for the first time Am-MOP with basic functional groups has been exploited for the Knoevenagel condensation reaction between aldehydes and active methylene compounds. Availability of a large number of catalytic sites per volume and confined microporosity gives enhanced catalytic efficiency and high selectivity for small substrate molecules." @default.
• W1991346145 created "2016-06-24" @default.
• W1991346145 creator A5013255727 @default.
• W1991346145 creator A5037629153 @default.
• W1991346145 creator A5052290692 @default.
• W1991346145 creator A5057150828 @default.
• W1991346145 creator A5081034587 @default.
• W1991346145 date "2014-03-28" @default.
• W1991346145 modified "2023-10-13" @default.
• W1991346145 title "Amide Functionalized Microporous Organic Polymer (Am-MOP) for Selective CO₂ Sorption and Catalysis" @default.
• W1991346145 cites W1909940713 @default.
• W1991346145 cites W1963984777 @default.
• W1991346145 cites W1965437736 @default.
• W1991346145 cites W1975618709 @default.
• W1991346145 cites W1979243460 @default.
• W1991346145 cites W1982990257 @default.
• W1991346145 cites W2000302001 @default.
• W1991346145 cites W2005606854 @default.
• W1991346145 cites W2006696967 @default.
• W1991346145 cites W2010190396 @default.
• W1991346145 cites W2011896776 @default.
• W1991346145 cites W2015428601 @default.
• W1991346145 cites W2022306081 @default.
• W1991346145 cites W2029513184 @default.
• W1991346145 cites W2029667189 @default.
• W1991346145 cites W2030867797 @default.
• W1991346145 cites W2037498998 @default.
• W1991346145 cites W2040111618 @default.
• W1991346145 cites W2048575095 @default.
• W1991346145 cites W2049145344 @default.
• W1991346145 cites W2052148555 @default.
• W1991346145 cites W2060333850 @default.
• W1991346145 cites W2061528716 @default.
• W1991346145 cites W2068552930 @default.
• W1991346145 cites W2074211433 @default.
• W1991346145 cites W2076662543 @default.
• W1991346145 cites W2077125801 @default.
• W1991346145 cites W2078096677 @default.
• W1991346145 cites W2079662446 @default.
• W1991346145 cites W2080893705 @default.
• W1991346145 cites W2084039082 @default.
• W1991346145 cites W2095089108 @default.
• W1991346145 cites W2105947666 @default.
• W1991346145 cites W2117666217 @default.
• W1991346145 cites W2119625859 @default.
• W1991346145 cites W2126430743 @default.
• W1991346145 cites W2134851411 @default.
• W1991346145 cites W2139758156 @default.
• W1991346145 cites W2141067506 @default.
• W1991346145 cites W2142141141 @default.
• W1991346145 cites W2149962227 @default.
• W1991346145 cites W2150697053 @default.
• W1991346145 cites W2313657079 @default.
• W1991346145 cites W2321939427 @default.
• W1991346145 cites W2322273113 @default.
• W1991346145 cites W2326172743 @default.
• W1991346145 cites W2330697122 @default.
• W1991346145 doi "https://doi.org/10.1021/am500057z" @default.
• W1991346145 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24641196" @default.
• W1991346145 hasPublicationYear "2014" @default.
• W1991346145 type Work @default.
• W1991346145 sameAs 1991346145 @default.
• W1991346145 citedByCount "121" @default.
• W1991346145 countsByYear W19913461452014 @default.
• W1991346145 countsByYear W19913461452015 @default.
• W1991346145 countsByYear W19913461452016 @default.
• W1991346145 countsByYear W19913461452017 @default.
• W1991346145 countsByYear W19913461452018 @default.
• W1991346145 countsByYear W19913461452019 @default.
• W1991346145 countsByYear W19913461452020 @default.
• W1991346145 countsByYear W19913461452021 @default.
• W1991346145 countsByYear W19913461452022 @default.
• W1991346145 countsByYear W19913461452023 @default.
• W1991346145 crossrefType "journal-article" @default.
• W1991346145 hasAuthorship W1991346145A5013255727 @default.
• W1991346145 hasAuthorship W1991346145A5037629153 @default.
• W1991346145 hasAuthorship W1991346145A5052290692 @default.
• W1991346145 hasAuthorship W1991346145A5057150828 @default.
• W1991346145 hasAuthorship W1991346145A5081034587 @default.
• W1991346145 hasConcept C161790260 @default.
• W1991346145 hasConcept C163638829 @default.
• W1991346145 hasConcept C168395250 @default.
• W1991346145 hasConcept C178790620 @default.
• W1991346145 hasConcept C185592680 @default.
• W1991346145 hasConcept C188027245 @default.
• W1991346145 hasConcept C192562407 @default.
• W1991346145 hasConcept C2777352791 @default.
• W1991346145 hasConcept C2778439535 @default.
• W1991346145 hasConcept C2778684945 @default.
• W1991346145 hasConcept C32909587 @default.
• W1991346145 hasConcept C86381522 @default.
• W1991346145 hasConceptScore W1991346145C161790260 @default.
• W1991346145 hasConceptScore W1991346145C163638829 @default.
• W1991346145 hasConceptScore W1991346145C168395250 @default.
• W1991346145 hasConceptScore W1991346145C178790620 @default.
• W1991346145 hasConceptScore W1991346145C185592680 @default.
• W1991346145 hasConceptScore W1991346145C188027245 @default.
• W1991346145 hasConceptScore W1991346145C192562407 @default.

• next