Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991348898> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W1991348898 endingPage "4906" @default.
- W1991348898 startingPage "4902" @default.
- W1991348898 abstract "2,4-Decadienal was heated under an inert atmosphere and in the presence of phenylalanine to investigate whether this secondary lipid oxidation product is a final product of lipid oxidation or it reacts with the amino acid. The results obtained showed that, in the presence of the alkadienal, the amino acid was degraded to styrene. This reaction was favored in dry systems at pH approximately 6 and in the absence of oxygen. If oxygen was present, the alkadienal was oxidized and the Strecker degradation of the amino acid was produced. The activation energy for the formation of styrene from phenylalanine was 150.4 kJ/mol. The reaction mechanism is suggested to be produced either by an electronic rearrangement of the imine produced between the aldehyde and the amino acid with the formation of styrene, 2-pentylpyridine, carbon dioxide, and hydrogen, or by Michael addition of the amino compound to the alkadienal followed by beta-elimination to produce the same compounds. Both reaction schemes were supported on the results obtained by studying both the degradation of phenylethylamine and phenylalanine methyl ester produced by 2,4-decadienal, and the formation of ethylbenzene in decadienal/phenylalanine reaction mixtures heated in the presence of platinum oxide. All these results suggest that, analogously to carbohydrates, certain lipid oxidation products may degrade appropriate amino acids to their corresponding vinylogous derivatives." @default.
- W1991348898 created "2016-06-24" @default.
- W1991348898 creator A5029816808 @default.
- W1991348898 creator A5030654510 @default.
- W1991348898 date "2007-05-09" @default.
- W1991348898 modified "2023-10-06" @default.
- W1991348898 title "Conversion of Phenylalanine into Styrene by 2,4-Decadienal in Model Systems" @default.
- W1991348898 cites W1974044537 @default.
- W1991348898 cites W1989855953 @default.
- W1991348898 cites W2021678969 @default.
- W1991348898 cites W2024805816 @default.
- W1991348898 cites W2038376311 @default.
- W1991348898 cites W2084423524 @default.
- W1991348898 cites W2093868285 @default.
- W1991348898 cites W2135948250 @default.
- W1991348898 cites W2158891552 @default.
- W1991348898 cites W2161287389 @default.
- W1991348898 cites W267911287 @default.
- W1991348898 cites W4255057469 @default.
- W1991348898 doi "https://doi.org/10.1021/jf070527w" @default.
- W1991348898 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17488119" @default.
- W1991348898 hasPublicationYear "2007" @default.
- W1991348898 type Work @default.
- W1991348898 sameAs 1991348898 @default.
- W1991348898 citedByCount "29" @default.
- W1991348898 countsByYear W19913488982012 @default.
- W1991348898 countsByYear W19913488982013 @default.
- W1991348898 countsByYear W19913488982014 @default.
- W1991348898 countsByYear W19913488982015 @default.
- W1991348898 countsByYear W19913488982016 @default.
- W1991348898 countsByYear W19913488982019 @default.
- W1991348898 countsByYear W19913488982020 @default.
- W1991348898 countsByYear W19913488982022 @default.
- W1991348898 countsByYear W19913488982023 @default.
- W1991348898 crossrefType "journal-article" @default.
- W1991348898 hasAuthorship W1991348898A5029816808 @default.
- W1991348898 hasAuthorship W1991348898A5030654510 @default.
- W1991348898 hasConcept C15920480 @default.
- W1991348898 hasConcept C161790260 @default.
- W1991348898 hasConcept C178790620 @default.
- W1991348898 hasConcept C185592680 @default.
- W1991348898 hasConcept C2777431362 @default.
- W1991348898 hasConcept C2777566558 @default.
- W1991348898 hasConcept C2777934754 @default.
- W1991348898 hasConcept C2779825165 @default.
- W1991348898 hasConcept C35378473 @default.
- W1991348898 hasConcept C515207424 @default.
- W1991348898 hasConcept C521977710 @default.
- W1991348898 hasConcept C55493867 @default.
- W1991348898 hasConceptScore W1991348898C15920480 @default.
- W1991348898 hasConceptScore W1991348898C161790260 @default.
- W1991348898 hasConceptScore W1991348898C178790620 @default.
- W1991348898 hasConceptScore W1991348898C185592680 @default.
- W1991348898 hasConceptScore W1991348898C2777431362 @default.
- W1991348898 hasConceptScore W1991348898C2777566558 @default.
- W1991348898 hasConceptScore W1991348898C2777934754 @default.
- W1991348898 hasConceptScore W1991348898C2779825165 @default.
- W1991348898 hasConceptScore W1991348898C35378473 @default.
- W1991348898 hasConceptScore W1991348898C515207424 @default.
- W1991348898 hasConceptScore W1991348898C521977710 @default.
- W1991348898 hasConceptScore W1991348898C55493867 @default.
- W1991348898 hasIssue "12" @default.
- W1991348898 hasLocation W19913488981 @default.
- W1991348898 hasLocation W19913488982 @default.
- W1991348898 hasOpenAccess W1991348898 @default.
- W1991348898 hasPrimaryLocation W19913488981 @default.
- W1991348898 hasRelatedWork W1861726583 @default.
- W1991348898 hasRelatedWork W1991348898 @default.
- W1991348898 hasRelatedWork W2014386371 @default.
- W1991348898 hasRelatedWork W2069624033 @default.
- W1991348898 hasRelatedWork W2093868285 @default.
- W1991348898 hasRelatedWork W2186410038 @default.
- W1991348898 hasRelatedWork W2328763573 @default.
- W1991348898 hasRelatedWork W2341584546 @default.
- W1991348898 hasRelatedWork W2528993768 @default.
- W1991348898 hasRelatedWork W2952812240 @default.
- W1991348898 hasVolume "55" @default.
- W1991348898 isParatext "false" @default.
- W1991348898 isRetracted "false" @default.
- W1991348898 magId "1991348898" @default.
- W1991348898 workType "article" @default.