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- W1991377662 abstract "Photochemical irradiation of the new bimetallic disilyliron complexes (SiMe2)[(η5-C5H4)Fe(CO)2SiMe2SiMe2R]2, R=Me, Ph, results in silylene elimination chemistry, as observed for the mono-metallic analogs, resulting in the formation of complexes (SiMe2)[(η5-C5H4)Fe(CO)2SiMe2R]2. The intermediate silyl(silylene) complexes can be intercepted with HMPA. Apart from a very reactive minor product that we have been unable to identify at this time, the proximity of the two transition metal centers has little impact upon the observed chemistry." @default.
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- W1991377662 date "2001-09-01" @default.
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- W1991377662 title "Photochemistry of bridged disilyldiiron complexes (SiMe2)[(η5-C5H4)Fe(CO)2SiMe2SiMe2R]2, R=Me, Ph" @default.
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- W1991377662 doi "https://doi.org/10.1016/s0022-328x(01)01094-4" @default.
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