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- W1991379863 abstract "Shock tube pyrolysis of propane at temperatures between 1300 and 2700 K at reflected shock pressures of 500 to 1500 kN/m 2 has been investigated. The reaction is of 1st order with a rate constant K = 1.79×10 8 exp (− 176.2 kJ/RT) s −1 . The major reaction products were acetylene, ethylene and methane, while traces of propylene and ethane were only detected at temperatures below 1500 K. At higher temperatures, propane conversion to acetylene increased at the expense of the other products. Optimum conversions to ethylene and methane, in contrast to that to acetylene, were more sensitive to changes in temperature than to variations in reaction time. However, at reaction pressures above 550 kN/m 2 , extension of reaction time beyond 0.5 ms did not favour the formation of acetylene. A simple kinetic model which confirmed the experimental optimum product selectivity conditions is put forward" @default.
- W1991379863 created "2016-06-24" @default.
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- W1991379863 date "1994-06-01" @default.
- W1991379863 modified "2023-09-25" @default.
- W1991379863 title "Pyrolysis of propane at reflected shock-wave temperatures from 1300 to 2700 K" @default.
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- W1991379863 doi "https://doi.org/10.1002/ceat.270170308" @default.
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