FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991391793> ?p ?o ?g. }

• W1991391793 endingPage "3499" @default.
• W1991391793 startingPage "3491" @default.
• W1991391793 abstract "The reactions between cis-Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) (1) or cis-Fe(PP3)H2 (PP3 = P(CH2CH2PMe2)3) (2) and phenyl isothiocyanate (PhNCS), ethyl isothiocyanate (EtNCS), and phenyl isocyanate (PhNCO) were investigated. PhNCS reacts with 1 to form a variety of insertion products at low temperature, and the thermodynamic product hydridoiron N-phenylthioformimidate trans-Fe(dmpe)2(SCHNPh)H (3a) at 300 K. Addition of an excess of PhNCS to 1 produces the bis(insertion) product trans-Fe(dmpe)2(SCHNPh)2 (3c). EtNCS inserts into the iron−hydride bond of 1 to form a mixture of trans-Fe(dmpe)2(SCHNEt)H (4a, thermodynamic product) and cis-Fe(dmpe)2(SCHNEt)H (4b, kinetic product). Addition of an excess of EtNCS does not result in a second insertion but rather attack at the thioformimidato ligand to form trans-Fe(dmpe)2(SCHN+(Et)C(S)N-Et)H (4c). PhNCO reacts rapidly with 1 to form trans-Fe(dmpe)2(OCHNPh)H (5a) and higher oligomeric products. The addition of PhNCS, EtNCS, and PhNCO to 2 permits the formation of thermally stable, geometrically constrained cis products cis-Fe(PP3)(SCHNPh)H (6a), cis-Fe(PP3)(SCHNEt)H (7a), and cis-Fe(PP3)(OCHNPh)H (8a) in clean reactions. The hydridoiron N-phenylthioformimidate 6a reacts with a second equivalent of PhNCS to form cis-Fe(PP3)(SCHNPh)2 (6c), but oligomerization of EtNCS or PhNCO does not occur. All complexes have been characterized by multinuclear NMR andIR spectroscopy and mass spectrometry (electrospray), with elemental analysis or high resolution mass spectrometry confirming the structures of thermally stable complexes where possible. Complexes 3c and 4c were characterized by single-crystal X-ray crystallography." @default.
• W1991391793 created "2016-06-24" @default.
• W1991391793 creator A5007029882 @default.
• W1991391793 creator A5080019417 @default.
• W1991391793 creator A5080663147 @default.
• W1991391793 date "2001-07-12" @default.
• W1991391793 modified "2023-10-03" @default.
• W1991391793 title "Addition of Nitrogen-Containing Heteroallenes to Iron(II)-Hydrides" @default.
• W1991391793 cites W1895493154 @default.
• W1991391793 cites W1964296875 @default.
• W1991391793 cites W1968674384 @default.
• W1991391793 cites W1969841323 @default.
• W1991391793 cites W1970814458 @default.
• W1991391793 cites W1971030478 @default.
• W1991391793 cites W1978443762 @default.
• W1991391793 cites W1987005237 @default.
• W1991391793 cites W1990550404 @default.
• W1991391793 cites W1993088982 @default.
• W1991391793 cites W1995529355 @default.
• W1991391793 cites W2001677318 @default.
• W1991391793 cites W2013308431 @default.
• W1991391793 cites W2015339255 @default.
• W1991391793 cites W2015947747 @default.
• W1991391793 cites W2017084386 @default.
• W1991391793 cites W2042870920 @default.
• W1991391793 cites W2045746149 @default.
• W1991391793 cites W2046556962 @default.
• W1991391793 cites W2051307280 @default.
• W1991391793 cites W2057338523 @default.
• W1991391793 cites W2058713040 @default.
• W1991391793 cites W2065335946 @default.
• W1991391793 cites W2069070890 @default.
• W1991391793 cites W2072613518 @default.
• W1991391793 cites W2077335288 @default.
• W1991391793 cites W2080182825 @default.
• W1991391793 cites W2081382661 @default.
• W1991391793 cites W2082619772 @default.
• W1991391793 cites W2083721980 @default.
• W1991391793 cites W2085624881 @default.
• W1991391793 cites W2120679271 @default.
• W1991391793 cites W2144332006 @default.
• W1991391793 cites W2512142927 @default.
• W1991391793 cites W2949408516 @default.
• W1991391793 cites W2950621033 @default.
• W1991391793 doi "https://doi.org/10.1021/om0100030" @default.
• W1991391793 hasPublicationYear "2001" @default.
• W1991391793 type Work @default.
• W1991391793 sameAs 1991391793 @default.
• W1991391793 citedByCount "27" @default.
• W1991391793 countsByYear W19913917932012 @default.
• W1991391793 countsByYear W19913917932016 @default.
• W1991391793 countsByYear W19913917932017 @default.
• W1991391793 countsByYear W19913917932020 @default.
• W1991391793 countsByYear W19913917932021 @default.
• W1991391793 countsByYear W19913917932022 @default.
• W1991391793 crossrefType "journal-article" @default.
• W1991391793 hasAuthorship W1991391793A5007029882 @default.
• W1991391793 hasAuthorship W1991391793A5080019417 @default.
• W1991391793 hasAuthorship W1991391793A5080663147 @default.
• W1991391793 hasConcept C116569031 @default.
• W1991391793 hasConcept C153642686 @default.
• W1991391793 hasConcept C155647269 @default.
• W1991391793 hasConcept C170493617 @default.
• W1991391793 hasConcept C176788430 @default.
• W1991391793 hasConcept C178790620 @default.
• W1991391793 hasConcept C185592680 @default.
• W1991391793 hasConcept C2776572452 @default.
• W1991391793 hasConcept C2777961443 @default.
• W1991391793 hasConcept C2779578285 @default.
• W1991391793 hasConcept C2780534471 @default.
• W1991391793 hasConcept C537208039 @default.
• W1991391793 hasConcept C544153396 @default.
• W1991391793 hasConcept C55493867 @default.
• W1991391793 hasConcept C66974803 @default.
• W1991391793 hasConcept C71240020 @default.
• W1991391793 hasConcept C8010536 @default.
• W1991391793 hasConceptScore W1991391793C116569031 @default.
• W1991391793 hasConceptScore W1991391793C153642686 @default.
• W1991391793 hasConceptScore W1991391793C155647269 @default.
• W1991391793 hasConceptScore W1991391793C170493617 @default.
• W1991391793 hasConceptScore W1991391793C176788430 @default.
• W1991391793 hasConceptScore W1991391793C178790620 @default.
• W1991391793 hasConceptScore W1991391793C185592680 @default.
• W1991391793 hasConceptScore W1991391793C2776572452 @default.
• W1991391793 hasConceptScore W1991391793C2777961443 @default.
• W1991391793 hasConceptScore W1991391793C2779578285 @default.
• W1991391793 hasConceptScore W1991391793C2780534471 @default.
• W1991391793 hasConceptScore W1991391793C537208039 @default.
• W1991391793 hasConceptScore W1991391793C544153396 @default.
• W1991391793 hasConceptScore W1991391793C55493867 @default.
• W1991391793 hasConceptScore W1991391793C66974803 @default.
• W1991391793 hasConceptScore W1991391793C71240020 @default.
• W1991391793 hasConceptScore W1991391793C8010536 @default.
• W1991391793 hasIssue "16" @default.
• W1991391793 hasLocation W19913917931 @default.
• W1991391793 hasOpenAccess W1991391793 @default.
• W1991391793 hasPrimaryLocation W19913917931 @default.
• W1991391793 hasRelatedWork W2027551269 @default.

• next